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DEME TFSI用于鎂電池添加劑

2018-06-19 16:46:51 adman 71

默尼,專業提供DEME TFSI及相關產品

DEME TFSI產品鏈接:http://m.ilschem.cn/mains/showproduct.php?lang=cn&id=44#ad-age-0

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Scientific Achievement

The effect of the addition of an ionic liquid DEME·TFSI to an electrolyte solution of Mg(HMDS)2-MgCl2 in THF was spectroscopically and electrochemically studied. Reversible magnesium deposition/dissolution and cycling of Mg-Mo6S8 coin cells were achieved with the DEME·TFSI-modified magnesium electrolyte.

Significance and Impact

Ionic liquids are thermally stable and non-volatile solvents, but they are largely incompatible with magnesium batteries. This study demonstrates the compatibility of the ionic liquid DEME·TFSI as an additive with magnesium deposition/dissolution and cycling of Mg-Mo6S8 coin cells, and provides insights to role of DEME·TFSI in the electrolyte.

Research Details

  • Addition of DEME·TFSI into Mg(HMDS)2-MgCl2/THF electrolyte enables higher ionic conductivity of the electrolyte, which facilitates magnesium deposition/dissolution.

  • Ionic conductivity measurements, cyclic voltammetry, SEM-EDS, NMR and Raman spectroscopy collectively suggest the role of DEME·TFSI in solution speciation of Mg(HMDS)2-MgCl2/THF electrolyte.


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